Tetra-μ-acetato-κ8 O:O′-bis[(3-cyanopyridine-κN 1)ruthenium(II,III)](Ru—Ru) hexafluoridophosphate 1,2-dichloroethane monosolvate
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چکیده
The title compound, [Ru(2)(CH(3)CO(2))(4)(C(6)H(4)N(2))(2)]PF(6)·C(2)H(4)Cl(2), was obtained via a rapid substitution reaction in 2-propanol whereby 3-cyano-pyridine replaces the axial water mol-ecules in the diaquatetra-μ-acetato-diruthenium(II,III) hexa-fluorido-phosphate starting material. The product rapidly precipated and crystals were grown from 1,2-dichloro-ethane. The 1,2-dichloro-ethane mol-ecule of solvation exhibits disorder with two different orientations [occupancy ratio 0.51 (6):0.49 (6)]. All three parts, the cation, the anion and the disordered solvent mol-ecule lie on crystallographic inversion centers. The Ru-Ru bond length of 2.2702 (6) Å fits nicely into the range seen for similar complexes and correlates well with the reduction potential of the complex and donor strength of the axial ligand, 3-cyano-pyridine, as postulated in a previous study [Vamvounis et al. (2000 ▶). Inorg. Chim. Acta, 305, 87-98]. The 3-cyano-pyridine ligands orient themselves in an anti configuration with respect to each other and the Ru-Ru-N angle [174.27 (7)°] is close to being linear.
منابع مشابه
Di-μ-acetato-κ4 O:O′-μ-oxido-κ2 O:O′-bis[cis-(2,2′-bipyridine-κ2 N,N′)-trans-(pyridine-κN)ruthenium(III)] bis(hexafluoridophosphate)
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